Ranu, Brindaban C. ; Bhadra, Sukalyan ; Adak, Laksmikanta (2008) Indium(III) chloride-catalyzed oxidative cleavage of carbon-carbon multiple bonds by tert-butyl hydroperoxide in water-a safer alternative to ozonolysis Tetrahedron Letters, 49 (16). pp. 2588-2591. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.02.089
Abstract
An efficient and general method for the oxidative cleavage of alkenes and alkynes using tert-butyl hydroperoxide and indium(III) chloride as catalyst in water to give the corresponding carboxylic acids or ketones has been achieved. The reaction conditions are compatible with sensitive moieties such as peptide bonds, tert-butyl carboxylic esters and N-Boc-protected tryptophan. The catalyst could be recycled.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Oxidative Cleavage; Alkenes; tert-butyl Hydroperoxide; Indium(III) Chloride; Water |
| ID Code: | 41453 |
| Deposited On: | 30 May 2011 05:32 |
| Last Modified: | 30 May 2011 05:32 |
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