Dey, Raju ; Chattopadhyay, Kalicharan ; Ranu, Brindaban C. (2008) Palladium(0) nanoparticle catalyzed cross-coupling of allyl acetates and aryl and vinyl siloxanes The Journal of Organic Chemistry, 73 (23). pp. 9461-9464. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo802214m
Related URL: http://dx.doi.org/10.1021/jo802214m
Abstract
The cross-coupling of allyl acetates and aryl and vinyl siloxanes proceeds readily by the catalysis of in situ generated palladium(0) nanoparticles. The reactions are stereoselective, and (E)-coupling products are obtained both from cis and trans allyl acetates. The coupling with vinyl siloxanes provides a novel protocol for the synthesis of 1,4-pentadienes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 41445 |
| Deposited On: | 30 May 2011 05:33 |
| Last Modified: | 30 May 2011 05:33 |
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