Saha, Amit ; Saha, Debasree ; Ranu, Brindaban C. (2009) Copper nano-catalyst: sustainable phenyl-selenylation of aryl iodides and vinyl bromides in water under ligand free conditions Organic & Biomolecular Chemistry, 7 (8). pp. 1652-1657. ISSN 1477-0520
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2009...
Related URL: http://dx.doi.org/10.1039/B819137A
Abstract
A simple and efficient procedure for the synthesis of aryl- and vinyl-selenides has been developed by a copper nanoparticle catalysed reaction of aryl iodide/vinyl bromide with diphenyl diselenide in the presence of zinc in water. (E)-Vinyl bromides produce (E)-vinyl selenides stereoselectively, whereas (Z)-vinyl bromides provide mixtures of (E) and (Z) isomers. The catalyst was recycled.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 41438 |
| Deposited On: | 30 May 2011 05:34 |
| Last Modified: | 30 May 2011 05:34 |
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