Hydroxyapatite-supported palladium-catalyzed efficient synthesis of (E)-2-alkene-4-ynecarboxylic esters. Intense fluorescene emission of selected compounds

Ranu, Brindaban C. ; Adak, Laksmikanta ; Chattopadhyay, Kalicharan (2008) Hydroxyapatite-supported palladium-catalyzed efficient synthesis of (E)-2-alkene-4-ynecarboxylic esters. Intense fluorescene emission of selected compounds The Journal of Organic Chemistry, 73 (14). pp. 5609-5612. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo800209z

Related URL: http://dx.doi.org/10.1021/jo800209z

Abstract

A simple procedure for the synthesis of substituted (E)-2-alkene-4-ynecarboxylic esters has been achieved using hydroxyapatite-supported palladium as efficient catalyst surface. The catalyst is recycled, and the turnover number (TON) based on Pd is 16000. A naphthyl-substituted derivative gives very intense fluorescence emission.

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ID Code:41432
Deposited On:30 May 2011 05:32
Last Modified:30 May 2011 05:32

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