Ghosh, Sudip ; Dey, Raju ; Chattopadhyay, Kalicharan ; Ranu, Brindaban C. (2009) Water-promoted highly regio- and stereoselective synthesis of α-dehydro-β-amino esters and nitriles from Baylis-Hillman acetates Tetrahedron Letters, 50 (34). pp. 4892-4895. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2009.06.051
Abstract
The nucleophilic addition of amines to Baylis-Hillman acetates has been efficiently carried out in water at room temperature in the absence of any base, acid, or metal catalyst to produce α-dehydro-β-amino esters and nitriles. This procedure addresses a variety of aliphatic open-chain and cyclic amines and anilines. All the reactions are highly regio- and stereoselective, fast and high yielding.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Baylis–Hillman Adduct; α-dehydro-β-amino Esters; Water; Regioselectivity; Stereoselectivity |
| ID Code: | 41429 |
| Deposited On: | 30 May 2011 05:34 |
| Last Modified: | 30 May 2011 05:34 |
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