Chavan, Suhas A. ; Srinivas, D. ; Ratnasamy, Paul (2001) A novel, zeolite-encapsulated μ3-oxo Co/Mn cluster catalyst for oxidation of para-xylene to terephthalic acid Chemical Communications (12). pp. 1124-1125. ISSN 1359-7345
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Official URL: http://pubs.rsc.org/en/content/articlelanding/2001...
Related URL: http://dx.doi.org/10.1039/B102016C
Abstract
Trinuclear, μ3-oxo mixed metal acetato complexes, [CoMn2(μ3-O)(MeCO2)6(py)3] (py = pyridine) encapsulated in zeolite HY, exhibit high catalytic efficiency in the selective aerial oxidation of para-xylene to terephthalic acid; interestingly, the formation of 4-carboxybenzaldehyde, the worrisome impurity in the conventional process, is suppressed significantly over these solid catalysts.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 41407 |
| Deposited On: | 28 May 2011 10:16 |
| Last Modified: | 28 May 2011 10:16 |
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