Experimental evidence for reversible zippering of chains in magnetic nanofluids under external magnetic fields

Abstract

We study the time-dependent transmitted intensity and the scattered pattern from magnetic nanofluids at constant ramping of uniform external magnetic field. The nanofluid used is the dispersion of magnetite particles with an average diameter of 6.5 nm with a protective surfactant coating. We observe several critical fields at which the transmitted light intensity decreases drastically followed by the formation of a ringlike pattern on a screen placed perpendicular to the field direction. Interestingly, the critical fields occur at a regular interval of 20 G. The observed critical fields are attributed to zippering transitions of the chains due to attractive energy well when the chains are of different lengths or shifted with respect to one another. Interaction energy calculations show a decrease in the energy of the system due to dipolar interactions at different critical fields confirming the lowering of the system energy through lateral coalescence. The observed zippering phenomenon is perfectly reversible.