Feuer, Henry ; Savides, Christos ; Rao, C. N. R. (1963) The infrared spectra of the salts of nitro compounds. Characteristic frequencies of the carbonitronate group, =C=NO2− Spectrochimica Acta, 19 (2). pp. 431-434. ISSN 0371-1951
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/037119...
Related URL: http://dx.doi.org/10.1016/0371-1951(63)80054-5
Abstract
The infrared spectra of salts of nitro compounds have been studied and the N-O asymmetric and symmetric stretchings of the carbonitronate ion have been assigned to the regions 1316-1205 and 1175-1040 cm−1. The C=N frequency of sodium alkanenitronates appears in the region 1605-1587 cm−1. The carbonyl and the nitrile stretching frequencies in α-nitroketones and α-nitronitriles are considerably reduced due to conjugation with the carbonitronate group.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 40096 |
| Deposited On: | 21 May 2011 08:47 |
| Last Modified: | 21 May 2011 08:47 |
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