Czanderna, A. W. ; Ramachandra Rao, C. N. ; Honig, J. M. (1958) The anatase-rutile transition. Part 1.-Kinetics of the transformation of pure anatase Transactions of the Faraday Society, 54 . pp. 1069-1073. ISSN 0014-7672
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1958...
Related URL: http://dx.doi.org/10.1039/TF9585401069
Abstract
Using spectroscopically pure anatase, the transition to rutile was investigated by means of X-ray spectra. Below 610°C the transition is immeasurably slow; above 730°C it occurs extremely rapidly. The conversion is second-order with respect to remaining anatase, and is characterized by an activation energy of ca. 100 Kcal/mole. A formal interpretation of these results is provided in terms of a model set forth by Avrami.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 40050 |
| Deposited On: | 21 May 2011 07:29 |
| Last Modified: | 26 May 2011 06:03 |
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