Vaidhyanathan, R. ; Natarajan, Srinivasan ; Rao, C. N. R. (2003) Open-framework cadmium succinates with interpenetrating frameworks formed by tetrahedral [ClCd4O24] and [BrCd4O24] clusters Crystal Growth & Design, 3 (1). pp. 47-51. ISSN 1528-7483
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/cg0200309
Related URL: http://dx.doi.org/10.1021/cg0200309
Abstract
By carrying out a metathetic reaction between sodium succinate and CdCl2 or CdBr2 in an n-butanol-water mixture, two novel open-framework cadmium succinates, [Na3Cd5(C4H4O4)6Cl], I, and [Na3Cd5(C4H4O4)6Br], II, have been isolated. Both of these compounds possess interpenetrating three-dimensional open-framework structures wherein tetrahedral Cl(Br)Cd4O24 clusters are connected by succinate linkages. The tetrahedral cluster itself is formed of four CdO6 octahedra surrounding a halogen atom. The three-dimensional cadmium succinate framework incorporates sodium ions. Four sodiums surround the second nearest neighbor halogen atom, forming a Na4Cl(Br) tetrahedron.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 40040 |
| Deposited On: | 21 May 2011 07:08 |
| Last Modified: | 22 Jul 2012 14:56 |
Repository Staff Only: item control page
