Ghosh, Anupama ; Rao, C. N. R. (2008) Chiral and achiral malate frameworks with different dimensionalities Zeitschrift für Anorganische und Allgemeine Chemie, 634 (6-7). pp. 1115-1122. ISSN 0044-2313
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.20...
Related URL: http://dx.doi.org/10.1002/zaac.200700582
Abstract
A hybrid chain compound of the formula [Sr(L-C4H4O5)·3H2O]·H2O (1) and a hybrid double layered compound of the formula [Pb(L- C4H4O5)] (2) both with chiral structures, have been prepared strarting with L- malic acid, and characterized by X-ray crystallography and other techniques. An achiral three-dimensional hybrid compound of the composition [Pb(D, L-C4H4O5)·2H2O] (3) has been obtained starting with D, L- malic acid. A chiral coordination polymer of CuII with the formula [Cu3(L-C4H3O5)2·4H2O]·2H2O (4) has also been characterized. The structures as well as the novel coordination modes exhibited by 1-4 are discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Malic Acid; Hybrid Compounds; Chirality; Strontium Malate; Lead Malate |
| ID Code: | 40021 |
| Deposited On: | 21 May 2011 06:42 |
| Last Modified: | 21 May 2011 06:42 |
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