Behera, J. N. ; Rao, C. N. R. (2005) Organically-templated zinc and thorium sulfates with chain and layered structures Zeitschrift für Anorganische und Allgemeine Chemie, 631 (15). pp. 3030-3036. ISSN 0044-2313
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.20...
Related URL: http://dx.doi.org/10.1002/zaac.200500302
Abstract
Amine-templated zinc sulfates of the formulae, [Zn(SO4)(H2O)2(C10N2H8)] (I) and [C3N2H12][Zn(SO4)] (II) both with linear structures have been prepared under hydro/solvothermal conditions. Of these, I has the chain structure formed by ZnO4N2octahedra and SO4 tetrahedra, while II comprises ladders formed by corner-sharing four-membered rings. Amine-templated thorium sulfates of the formula [HN(CH2)6NH]2[Th2(SO4)6(H2O)2]·2H2O, (III) and [H2N(CH2)4NH2][Th3(SO4)7(H2O)4]·5H2O (IV) are also obtained under hydrothermal conditions. III has a sheet structure consisting of cages whereas IV has a two-dimensional structure derived from the connectivity of ladders.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | Open-framework Structures; Zinc Sulfate; Thorium Sulfate; Hydro/Solvothermal Synthesis |
| ID Code: | 39977 |
| Deposited On: | 20 May 2011 12:20 |
| Last Modified: | 20 May 2011 12:20 |
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