Probing the structure and crystallinity of a lithium silicate glass by 29Si magic-angle-spinning NMR spectroscopy

Rao, C. N. R. ; Thomas, John M. ; Klinowski, Jacek ; Selvaraj, U. ; Rao, K. J. ; Robert Millward, G. ; Ramdas, Subramaniam (1985) Probing the structure and crystallinity of a lithium silicate glass by 29Si magic-angle-spinning NMR spectroscopy Angewandte Chemie International Edition, 24 (1). pp. 61-62. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...

Related URL: http://dx.doi.org/10.1002/ejic.200390218

Abstract

The short-range order in noncrystalline and crystalline silicates can be investigated with 29Si magic-angle-spinning (MAS) NMR spectroscopy. Different 29Si chemical shifts are observed depending on the degree of cross-linkage of the silicate, the Si—O—Si bond angles, and the interatomic distances. In this way, the distribution of Si—O—Si angles in glasses, the crystallinity of which lies between 0 and 100%, can be obtained.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons.
ID Code:39972
Deposited On:20 May 2011 10:12
Last Modified:17 May 2016 22:14

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