Basavaiah, Deevi ; Sreenivasulu, Bandaru ; Reddy, Ravi Mallikarjuna ; Muthukumaran, Kannan (2001) The Baylis-Hillman reaction: TiCl4 mediated coupling of alkyl vinyl ketones with α-keto esters and aldehydes Synthetic Communications, 31 (19). pp. 2987-2995. ISSN 0039-7911
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Official URL: http://www.informaworld.com/index/713939660.pdf
Related URL: http://dx.doi.org/10.1081/SCC-100105670
Abstract
TiCl4 mediated coupling of alkyl vinyl ketones with α-keto esters and aldehydes provides respectively 2-aryl-2-hydroxy-3-methylene-4-oxoalkanoates and (Z)-keto allyl chlorides in 1 h time at room temperature. Similar coupling of trifluoromethyl phenyl ketone with methyl vinyl ketone produces 1,1,1-trifluoro-2-hydroxy-2-phenyl-3-methylenepentan-4-one.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 3903 |
| Deposited On: | 18 Oct 2010 09:28 |
| Last Modified: | 16 May 2016 14:36 |
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