Basavaiah, Deevi ; Krishna, Peddinti Rama ; Bharathi, Tirumala K. (1995) A convenient enantioselective synthesis of trans-2-aryloxycyclohexan-1-ols using pig liver acetone powder (PLAP) as biocatalyst Tetrahedron: Asymmetry, 6 (2). pp. 439-454. ISSN 0957-4166
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/095741...
Related URL: http://dx.doi.org/10.1016/0957-4166(95)00029-O
Abstract
Pig liver acetone powder (PLAP) has been used as a biocatalyst for enantioselective hydrolysis of racemic trans-1-acetoxy-2-aryloxycyclohexannes to produce the resulting (R,R)-2-aryloxycyclohexan-1-ols upto > 99% enantiomeric purities. (R,R)-Selectivity in this hydrolysis of racemic trans-2-aryloxycyclohexyl acetates was explained on the basis of Jones' three dimensional active site-model.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 3895 |
| Deposited On: | 18 Oct 2010 09:29 |
| Last Modified: | 18 Oct 2010 09:29 |
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