Rama Rao, A. V. ; Sharma, G. V. M. ; Bhanu, Manjunath N. (1992) Radical mediated enantioselective construction of C-1 to C-9 segment of rhizoxin Tetrahedron Letters, 33 (27). pp. 3907-3910. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)74816-7
Abstract
A highly enantioselective route has been devised for the synthesis of the 3,5 cis̲-disubstituted valerolactone moiety (C-1 to C-9 segment) of rhizoxin via̲ intramolecular radical cyclisation of suitably functionalised 6-heptenyl radical.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | 6-Heptenyl Radical; cis̲-Disubstituted Valerolactone; Mixed Bromoacetals; Intramolecular Radical Cyclisation |
| ID Code: | 38853 |
| Deposited On: | 05 May 2011 06:49 |
| Last Modified: | 05 May 2011 06:49 |
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