Phenethylamine in a rigid framework: synthesis, stereochemistry and reactions of cis and trans-4-amino-2,3,4,5-tetrahydro-1-benzoxepin-5-ols and their derivatives

Tandon, V. K. ; Khanna, J. M. ; Chandra, Animesh ; Anand, Nitya (1990) Phenethylamine in a rigid framework: synthesis, stereochemistry and reactions of cis and trans-4-amino-2,3,4,5-tetrahydro-1-benzoxepin-5-ols and their derivatives Tetrahedron, 46 (8). pp. 2871-2882. ISSN 0040-4020

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)88379-4

Abstract

Cis- and trans-amino alcohols 1α and 2α and their derivatives have been synthesised and their stereochemistry studied. Stereochemical studies have shown that cis- isomer is thermodynamically more favoured than the trans- isomer.

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