Basavaiah, Deevi ; Reddy, Gone Jayapal ; Chandrashekar, Vanampally (2001) A novel and effective chiral phosphoramide catalyst for the borane-mediated asymmetric reduction of prochiral α-halo ketones Tetrahedron: Asymmetry, 12 (4). pp. 685-689. ISSN 0957-4166
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09574...
Related URL: http://dx.doi.org/10.1016/S0957-4166(01)00101-X
Abstract
The novel chiral phosphoramide, 1,4-bis[(5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo(3.3.0)octan-2-yl]piperazine, was synthesised and successfully employed as a catalyst in the borane-mediated asymmetric reductions of prochiral α-halo ketones, providing the corresponding α-halo alcohols in 90-95% enantiomeric purities.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 3865 |
| Deposited On: | 18 Oct 2010 09:34 |
| Last Modified: | 17 Jan 2011 05:40 |
Repository Staff Only: item control page
