Basavaiah, Deevi ; Kumaragurubaran, Nagaswamy ; Sharada, Duddu S. ; Reddy, Ravi Mallikarjuna (2001) Applications of Baylis-Hillman chemistry: enantioselective synthesis of (-)-methyl 3-aryl-2-methylene-3-(prop-2-yn-1-yloxy)propanoates via chiral leaving group strategy Tetrahedron, 57 (38). pp. 8167-8172. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)00786-4
Abstract
Asymmetric synthesis of (-)-methyl 3-aryl-2-methylene-3-(prop-2-yn-1-yloxy)propanoates in 25-40% enantiomeric purities via the reaction of methyl (2Z)-3-aryl-2-(bromomethyl)prop-2-enoates with prop-2-yn-1-ol in the presence of quinidine is described.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Baylis-Hillman Chemistry; Methyl 3-aryl-2-methylene-3-(prop-2-yn-1-yloxy)propanoates; Chiral Leaving Group |
| ID Code: | 3860 |
| Deposited On: | 18 Oct 2010 09:35 |
| Last Modified: | 18 Oct 2010 09:35 |
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