Toward effective chiral catalysts containing the N---P=O structural framework for the borane-mediated asymmetric reduction of prochiral ketones

Basavaiah, Deevi ; Reddy, Gone Jayapal ; Rao, Kalapala Venkateswara (2004) Toward effective chiral catalysts containing the N---P=O structural framework for the borane-mediated asymmetric reduction of prochiral ketones Tetrahedron: Asymmetry, 15 (12). pp. 1881-1888. ISSN 0957-4166

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09574...

Related URL: http://dx.doi.org/10.1016/j.tetasy.2004.05.011

Abstract

Representative chiral catalysts containing the N---P=O structural framework having (5S)-1,3-diaza-2-phospha-2-oxo-3-phenylbicyclo[3.3.0]octane moiety with amino groups of varying steric requirements on phosphorus, have been synthesized and their applications in the borane-mediated asymmetric reduction of prochiral ketones described.

Item Type:Article
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Deposited On:18 Oct 2010 09:37
Last Modified:18 Oct 2010 09:37

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