Basavaiah, Deevi ; Das, Utpal ; Roy, Suparna (2009) Towards chiral diamines as chiral catalytic precursors for the borane-mediated enantioselective reduction of prochiral ketones Journal of Chemical Sciences, 121 (6). pp. 1003-1010. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/chemsci/Pdf-Nov2009/1003.pdf
Related URL: http://dx.doi.org/10.1007/s12039-009-0112-x
Abstract
Two chiral diamines (3S)-3-anilinomethyl-1,2,3,4-tetrahydroisoquinoline (1) and (2R)-2-anilinomethylpiperidine (2) have been employed as chiral catalytic sources in the borane-mediated asymmetric reduction of prochiral ketones thus providing the resulting secondary alcohols in good enantiomeric purities (up to 81% ee).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | (3S)-3-Anilinomethyl-1,2,3,4-tetrahydroisoquinoline; (2R)-2-anilinomethylpiperidine; (S)-phenylalanine; Asymmetric Reduction |
| ID Code: | 3847 |
| Deposited On: | 18 Oct 2010 09:37 |
| Last Modified: | 16 May 2016 14:34 |
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