Periasamy, N. ; Santhanam, K. S. V. (1976) Emission from an excited triplet state during ECL Chemical Physics Letters, 39 (2). 265-268 . ISSN 0009-2614
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(76)80070-X
Abstract
The application of Marcus theory of electron transfer reactions for the case of radical ion chemiluminescence of 9,10-diphenylanthracene (DPA) gives a high rate constant value (109-1010 M-1 s-1) for the formation of the second triplet state (T2). It is suggested that the near infrared emission observed during electrochemiluminescence of DPA is due to T2→T1 fluorescence based on the high yield of T2 (≈0.7) in the electron transfer reaction.
Item Type: | Article |
---|---|
Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 38023 |
Deposited On: | 20 Apr 2011 11:48 |
Last Modified: | 20 Apr 2011 11:48 |
Repository Staff Only: item control page