The behaviour of lead in iodide medium at the dropping mercury electrode. I.D.C. polarographic study

Srinivasan, V. S. ; Sundaram, A. K. (1962) The behaviour of lead in iodide medium at the dropping mercury electrode. I.D.C. polarographic study Australian Journal of Chemistry, 15 (4). pp. 729-733. ISSN 0004-9425

Full text not available from this repository.

Official URL: http://www.publish.csiro.au/?paper=CH9620729

Related URL: http://dx.doi.org/10.1071/CH9620729

Abstract

The polarography of lead in the iodide medium has shown that an irreversible wave is obtained at moderate concentrations of lead, whereas at high concentrations two waves are obtained and at low concentrations a single reversible wave is obtained. This explains the irreversible waves obtained by the earlier workers who have mainly worked in the region of 0.4mM of lead. From a study of the effect of the head of mercury, temperature, etc. it is shown that the second wave is an adsorption wave resulting from the adsorption of lead iodide complexes at the dropping mercury electrode.

Item Type:Article
Source:Copyright of this article belongs to Commonwealth Scientific and Industrial Research Organisation Publishing.
ID Code:37743
Deposited On:21 Apr 2011 05:54
Last Modified:21 Apr 2011 05:54

Repository Staff Only: item control page