Periasamy, N. ; Linschitz, Henry (1979) Cage escape and spin rephasing of triplet ion-radical pairs: temperature-viscosity and magnetic field effects in photoreduction of fluorenone by dabco Chemical Physics Letters, 64 (2). pp. 281-285. ISSN 0009-2614
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/000926...
Related URL: http://dx.doi.org/10.1016/0009-2614(79)80513-8
Abstract
Weak magnetic fields are found to increase the bulk ion-radical yield from a triplet radical pair, in temperature-viscosity region where cage recombination occurs. The results are consistent with Noyes' theory of geminate reactions and a hyperfine coupling mechanism for spin inversion leading to quenching.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 37529 |
| Deposited On: | 20 Apr 2011 11:48 |
| Last Modified: | 20 Apr 2011 11:48 |
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