New chiral titanium complexes for enantioselective reductive cyclizations of diimines to trans-2,3-diarylpiperazines

Vairaprakash, Pothiappan ; Periasamy, Mariappan (2008) New chiral titanium complexes for enantioselective reductive cyclizations of diimines to trans-2,3-diarylpiperazines Tetrahedron Letters, 49 (7). 1233-1236 . ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2007.12.038

Abstract

Enantioselective intramolecular reductive coupling of diimines by chiral titanium complexes, prepared using a titanium(IV) reagent and hemisalen ligands derived from chiral β-amino alcohols, gives trans-2,3-diarylpiperazines in up to 97% ee.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Enantioselective Reductive Coupling; Diimine; Hemisalen Ligand; 2,3-Diarylpiperazines
ID Code:37276
Deposited On:25 Apr 2011 08:08
Last Modified:25 Apr 2011 08:08

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