Ariamala, G. ; Sumathi, T. ; Balasubramanian, K. K. (1992) Photochemical studies on 3,4-epoxy-3,4-dihydro-2H-1-benzopyrans Proceedings of the Indian Academy of Sciences - Chemical Sciences, 104 (6). pp. 753-757. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/104/6/753-7...
Related URL: http://dx.doi.org/10.1007/BF02839122
Abstract
Photochemical behaviour of 3,4-epoxy-3,4-dihydro-2H-1-benzopyrans, intermediates in the synthesis of pterocarpans, has been studied in various solvents. While ring contraction leading to 2,3-dihydrobenzofurans through a photodecarbonylation process was observed in cyclohexane, photoisomerisation leading to 3-chromanones was observed in acetone. This study has also been extended to antijuvenile hormone precocene(I) oxide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | 3,4-Epoxy-3; 4-Dihydro-2h-1-benzopyran; Pterocarpan; Photodecarbonylative Ring Contraction; Photoisomerisation; δ' Hydrogen Abstraction; Precocene(I) Oxide |
| ID Code: | 3726 |
| Deposited On: | 18 Oct 2010 09:56 |
| Last Modified: | 16 May 2016 14:28 |
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