Rama Reddy, Malladi ; Periasamy, Mariappan (1995) Isomerization of 1-alkenes using the Na2Fe(CO)4/CuCl and Na2Fe(CO)4/BrCH2CH2 Br reagent systems Journal of Organometallic Chemistry, 491 (1-2). 263-266 . ISSN 0022-328X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002232...
Related URL: http://dx.doi.org/10.1016/0022-328X(94)05243-5
Abstract
The reagent Na2Fe(CO)4 prepared in situ in THF by the reduction of Fe(CO)5 with sodium naphthalenide reacts with certain alkenes in the presence of CuCl to bring about isomerization of the alkenes. Thus the 1-alkenes (1-dodecene, 1-decene, safrole and allyl benzene) are isomerized to trans-2-alkenes, and β-pinene is isomerized to α-pinene. Reactions involving BrCH2CH2Br in place of CuCl give similar results.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Isomerization; Supernucleophile; Iron Tetracarbonyl; Iron-copper Bonds; Iron Pentacarbonyl; Copper(I) Chloride |
| ID Code: | 37202 |
| Deposited On: | 25 Apr 2011 08:04 |
| Last Modified: | 25 Apr 2011 08:04 |
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