Studies in the claisen rearrangement. Part XII. Synthesis of benzofuro[3,2-c] [l]-6a,lladihydro-lla-methylbenzopyrans from 1,4-diaryloxy-2-butynes

Majumdar, K. C. ; Thyagarajan, B. S. ; Balasubramanian, K. K. (1973) Studies in the claisen rearrangement. Part XII. Synthesis of benzofuro[3,2-c] [l]-6a,lladihydro-lla-methylbenzopyrans from 1,4-diaryloxy-2-butynes Journal of Heterocyclic Chemistry, 10 (2). pp. 159-164. ISSN 0022-152X

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/jhet.55...

Related URL: http://dx.doi.org/10.1002/jhet.5570100205

Abstract

Successful Claisen rearrangement of a number of 1,4-diaryloxy-2-butynes is reported. The products of such a rearrangement are the benzofuro[3,2-c]benzopyrans. This novel rearrangement offers a facile synthetic route to tetracyclic derivatives resembling the naturally occurring pterocarpans.

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