A convenient method for the synthesis and resolution of Tröger base

Satishkumar, Sakilam ; Periasamy, Mariappan (2006) A convenient method for the synthesis and resolution of Tröger base Tetrahedron: Asymmetry, 17 (7). pp. 1116-1119. ISSN 0957-4166

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S09574...

Related URL: http://dx.doi.org/10.1016/j.tetasy.2006.04.002

Abstract

Racemic Tröger base 1 can be readily obtained by the condensation of 4-toluidine and paraformaldehyde in the presence of Lewis acids and easily resolved via the preparation of diastereomeric aggregates using chiral dibenzoyl-l-tartaric acid 2.

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ID Code:37135
Deposited On:25 Apr 2011 08:08
Last Modified:25 Apr 2011 08:08

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