Novel Reaction of the [HFe3(CO)11]- reagent with alkynes: a new synthesis of cyclobutenediones

Periasamy, Mariappan ; Rameshkumar, Chellappan ; Radhakrishnan, Ukkiramapandian (1997) Novel Reaction of the [HFe3(CO)11]- reagent with alkynes: a new synthesis of cyclobutenediones Tetrahedron Letters, 38 (41). 7229-7232 . ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(97)01677-8

Abstract

Reaction of the [HFe3(CO)11]- species generated in situ using Fe(CO)5 and NaBH4/CH3COOH in THF with alkynes, followed by CuCl2.2H2O oxidation leads to the corresponding cyclobutenediones in 60–73% yields. Reaction of [HFe3(CO)11]- species, generated in situ using Fe(CO)5 and NaBH4/CH3COOH in THF, with alkynes followed by CuCl2·2H2O oxidation leads to the corresponding cyclobutenedione.

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