Vithal, M. ; Srinivasulu, B. ; Koteswara Rao, K. ; Mohan Rao, Ch. (2000) Preparation, characterization, ESR and PAS studies of Cu0.5NbAlP3O12 and HNbAlP3O12 Materials Letters, 45 (1). pp. 58-62. ISSN 0167-577X
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S01675...
Related URL: http://dx.doi.org/10.1016/S0167-577X(00)00075-6
Abstract
New sodium super ionic conductor (NASICON) type niobium aluminum phosphates of composition Cu0.5NbAlP3O12 (CNP) and HNbAlP3O12 (HNP) are prepared. The compounds are isomorphous with NbTiP3O12 and unit cell parameters are evaluated. Copper and hydrogen occupy the channels. Reduction of CNP gives rise to HNP. electron spin resonance (ESR) and photo acoustic (PA) spectral data are consistent with elongated octahedral configuration around Cu2+ ion.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | NASICON; Powder XRD; Electron Spin Resonance; Photoacoustic Spectra |
| ID Code: | 36842 |
| Deposited On: | 16 Apr 2011 14:05 |
| Last Modified: | 29 Nov 2011 10:04 |
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