Das, Radha R. ; Bhat, T. R. ; Shankar, J. (1968) Kinetics of exchange of aluminium ethylenediaminetetraacetate with iron(III), nickel(II) and cobalt(II) Journal of Inorganic and Nuclear Chemistry, 30 (7). pp. 1691-1698. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(68)80340-9
Abstract
The kinetics of exchange in Al(EDTA) with different cations like Fe3+, Co2+ and Ni2+ has been studied by measuring the optical absorbance of the system using a Beckman DU Spectrophotometer. The reactions follow first order kinetics. The energy of activation for the different systems is the same and is equal to 12.5±0.5 kcal/mole. The mechanism of the exchange reactions is discussed. Evidence supporting the dimeric nature of Al (EDTA) has also been discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 35862 |
| Deposited On: | 11 Apr 2011 13:29 |
| Last Modified: | 11 Apr 2011 13:29 |
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