Ranganathan, Darshan ; Kurur, Sunita ; Madhusudanan, K. P. ; Roy, Raja ; Karle, Isabella L. (1998) Self-assembling bis-dendritic peptides: design, synthesis and characterization of oxalyl-linked bis-glutamyl peptides [Glun(CO2Me)n+1-CO-]2; n = 1,3,7 Journal of Peptide Research, 51 (4). pp. 297-302. ISSN 1397-002X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1111/j.1399-...
Related URL: http://dx.doi.org/10.1111/j.1399-3011.1998.tb00427.x
Abstract
Three generations of glutamic acid dendrons [Gluη(CO2Me)η+1; η = 1,3,7] have been joined together head-to-head by an oxalyl unit to form highly sterically congested bis-Glu-dendritic peptides with gelling properties. The single crystal X-ray structure of the first generation bis-dendritic peptide showed an extended hydrogen-bonded chiral tape with modest nonlinear optical activity.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| Keywords: | X-ray Diffraction Analysis; Hydrogen Bonded Chiral Tape; Supramolecular Aggregation; Self-complementary Hydrogen Bonding |
| ID Code: | 35402 |
| Deposited On: | 17 May 2011 10:33 |
| Last Modified: | 17 May 2011 10:33 |
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