Pramanick, Dinabandhu ; Palit, Santi R. (1971) Studies in some new initiator systems for vinyl polymerization. IV. Amino acids as the reducing component Journal of Polymer Science Part A-1: Polymer Chemistry, 9 (4). pp. 1005-1012. ISSN 0449-296X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pol.197...
Related URL: http://dx.doi.org/10.1002/pol.1971.150090415
Abstract
Amino acids have been found to form good redox initiator systems with halogens (Cl2 and Br2), KBrO3, KMnO4, and Fe(NH4)(SO4)2. The three systems, viz., glycine–Cl2, taurine-Cl2, and sulfamic acid-Cl2 incorporate amine, carboxy (or sulfoxy), chlorine, and hydroxy endgroups in the resulting polymers, the monomer investigated being mainly methyl methacrylate. On the basis of endgroup results it is suggested that initiation through amino acid radical, chlorine radical and also through some hydroxyl radicals takes place. The probable termination mechanism is discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 33806 |
| Deposited On: | 29 Mar 2011 14:07 |
| Last Modified: | 29 Mar 2011 14:07 |
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