Mitra, Bhairab Chandra ; Chadha, Subhash Chander ; Ghosh, Premamoy ; Palit, Santi R. (1966) Studies on some radical transfer reactions. Part I. Hydrogen atom abstraction from some organic substrates by ȮH radicals Journal of Polymer Science Part A-1: Polymer Chemistry, 4 (4). pp. 901-906. ISSN 0449-296X
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pol.196...
Related URL: http://dx.doi.org/10.1002/pol.1966.150040415
Abstract
Polymerization of methyl methacrylate was carried out in aqueous and nonaqueous media in the presence of some sulfonated and carboxylic organic compounds, hydroxyl radicals generated from hydrogen peroxide being used as initiators of polymerization. The occurrence of radical transfer reactions by way of hydrogen atom abstraction from the organic substrates by the ȮH radicals was demonstrated by the detection of sulfonate and carboxyl endgroups in the respective polymers. It was found that the radical transfer reactions were more favored in aqueous media than in nonaqueous systems.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 33805 |
| Deposited On: | 29 Mar 2011 13:41 |
| Last Modified: | 29 Mar 2011 13:41 |
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