Studies in the complexes of anthrones with metal halides-IV complexes of anthrones with the halides of iodine (I), zinc, mercury (II), boron and aluminium

Paul, Ram Chand ; Parkash, Ram ; Sandhu, Sarjit Singh (1967) Studies in the complexes of anthrones with metal halides-IV complexes of anthrones with the halides of iodine (I), zinc, mercury (II), boron and aluminium Journal of Inorganic and Nuclear Chemistry, 29 (8). pp. 1915-1920. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(67)80450-0

Abstract

Benzanthrone, anthrone, 10-nitroanthrone, 10-benzalanthrone and 10,10-dibenzylanthrone from 1:1 complexes with some of the halides of iodine (I), zinc, mercury (II), boron and aluminium. The molar conductance of iodine (I) halide complexes in nitrobenzene suggests that although the complexes are not strictly uni-univalent electrolytes yet they are appreciably ionized. The i.r. spectra of benzanthrone complexes of iodine (I) and mercury (II) halides indicate that the bond formation is through the carbonyl oxygen and that the chlorides appear to be stronger electron acceptors than the corresponding bromides.

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