Paul, Ram Chand ; Kumar, R. C. ; Verma, Rajendar Dev (1978) Complexes of dichlorobis(halosulphato)titanium(IV) with pyridine, quinoline, dimethyl sulphoxide and acetylacetone Journal of the Less Common Metals, 58 (1). pp. 1-6. ISSN 0022-5088
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002250...
Related URL: http://dx.doi.org/10.1016/0022-5088(78)90065-6
Abstract
The position of the various infrared bands in the spectra of dichlorobis-(halosulphato) titanium(IV), TiCl2(SO3X)2 with X=F, Cl, indicates the bidentate nature of the halosulphate groups. They form 1:1 adducts with pyridine, quinoline and dimethyl sulphoxide. The infrared spectra of these complexes indicate the monodentate nature of the halosulphate groups. The infrared spectra of TiCl2(SO3X)2·DMSO indicate that the coordination of dimethyl sulphoxide is through its oxygen atom and not through the sulphur atom. Acetylacetone reacts with dichlorobis(halosulphato)titanium(IV) giving Ti(acac)2(SO3X)2 which have also been characterized from their infrared spectra.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 33466 |
| Deposited On: | 31 Mar 2011 08:57 |
| Last Modified: | 31 Mar 2011 08:57 |
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