Chemistry of substituted sulphuric acids. X. Acids and bases in methanesulphuric acid solvent system

Paul, Ram Chand ; Kapila, V. P. ; Kumar, R. ; Gupta, S. K. ; Sharma, S. K. (1980) Chemistry of substituted sulphuric acids. X. Acids and bases in methanesulphuric acid solvent system Zeitschrift fur anorganische und allgemeine Chemie, 471 (1). pp. 203-207. ISSN 0044-2313

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.19...

Related URL: http://dx.doi.org/10.1002/zaac.19804710123

Abstract

Methanesulphuric acid is weaker than sulphuric acid. A number of inorganic protonic acids act as acids in it while the strong bases are fully protonated. The acid-base titrations in it with strong acids indicate that the bulk of the current is carried by CH3SO3H2+ and CH3SO3- ions. The conductance measurements indicate that the order of the acid strength is: H[B(HSO4)4] > HSO3F > H2S2O7 > HAs(HSO4)4 > HSO3Cl > H2SO4 > HX (X=Br > Cl) > H2SeO4.

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