Vibrational spectra of fluorinated aromatics. X. p-fluorochloro-, p-fluorobromo-, and p-fluoroiodobenzene

Narasimham, N. A. ; El-Sabban, M. Z. ; Rud Nielsen, J. (1956) Vibrational spectra of fluorinated aromatics. X. p-fluorochloro-, p-fluorobromo-, and p-fluoroiodobenzene The Journal of Chemical Physics, 24 (2). pp. 420-432. ISSN 0021-9606

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Official URL: http://link.aip.org/link/JCPSA6/v24/i2/p420/s1

Related URL: http://dx.doi.org/10.1063/1.1742491

Abstract

The infrared absorption spectra of liquid p-fluorochloro-, p-fluorobromo-, and p-fluoroiodobenzene, and the stronger bands of the first two compounds in the gaseous state, have been obtained in the region 2-38μ with NaCl and CsBr prisms. The Raman spectra of the compounds in the liquid state have been photographed with a 3-prism glass spectrograph of linear dispersion 15 A/mm at 4358 A, and depolarization ratios have been measured for the stronger Raman bands of p-fluorochloro- and p-fluorobromobenzene. Complete assignments of the fundamental vibrational frequencies have been made, and the spectra are interpreted in detail.

Item Type:Article
Source:Copyright of this article belongs to American Institute of Physics.
ID Code:33435
Deposited On:31 Mar 2011 09:03
Last Modified:31 Mar 2011 09:03

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