Sudha, B. P. ; Dixit, N. S. ; Patel, C. C. (1978) Reactions of bis(isonitrosoethylacetoacetato)palladium(II) with straight chain aliphatic primary amines influence of concentration of the reacting amines on the nature of the products Zeitschrift fur anorganische und allgemeine Chemie, 444 (1). pp. 237-242. ISSN 0044-2313
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/zaac.19...
Related URL: http://dx.doi.org/10.1002/zaac.19784440126
Abstract
Reactions of bis(isonitrosoethylacetoacetato)palladium(II), Pd(IEAA)2, with straight chain non-bulky alkylamines, R-NH2(R = CH3, C2H5, n-C3H7 or n-C4H9) in the mole ratio 1:1 gave bis (B-alkyl isonitrosoethylacetoacetateimino)Palladium(II), Pd(R-IEAI)2. In this reaction the coordinated carbonyl groups of Pd(IEAA)2 undergo condensation with amines forming Schiff bases (>CN=R). On the other hand, the reactions of Pd(IEAA)2 with a large excess of amine yielded N-alkylamido bridged isonitrosoethylacetoacetatedipalladium(II), μ-(NHR)2[Pd(IEAA)]2 complexes. The complexes are characterized by elemental analyses, magnetic susceptibility, i.r., p.m.r. and in some cases, nitrogen 1s X-ray photoelectron and mass spectral studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 33241 |
| Deposited On: | 30 Mar 2011 13:23 |
| Last Modified: | 10 Jun 2011 05:27 |
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