Patel, C. C. ; Jere, G. V. (1963) Nature, stability and bonding of the peroxy group in peroxy titanium compounds Journal of Inorganic and Nuclear Chemistry, 25 (9). pp. 1155-1159. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(63)80137-2
Abstract
Some physicochemical properties of peroxy titanium compounds are explained by assigning a strained triangular ring structure to the peroxy titanyl group, with a bent and reduced overlap of the O-O bonding orbitals. The stability of the peroxy group is found to depend on the stability of the other ligands. The decreasing order of stability of the peroxy group in the compounds is as: oxalato > meleato > malonato > sulphato > peroxide of titanium.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 33235 |
| Deposited On: | 30 Mar 2011 13:22 |
| Last Modified: | 10 Jun 2011 06:12 |
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