Diphenyl sulphoxide complexes of some divalent metal ions

Abstract

Diphenyl sulphoxide (DPSO) complexes of some divalent metal perchlorates and chlorides are prepared The perchlorates of Mn, Co, Ni, Zn and Cd have the general formula [M(DPSO)₆](CIO₄)₂. The Cu(II) complex is found to have the composition [Cu(DPSO)₄] (CIO₄₂. The chloro complex having the formula ZnCl₂. 2DPSO, CdCl₂.DPSO, HgCl₂. DPSO and PdCl₂. 2 DPSO have also been obtained. Infrared spectra indicate that the DPSO complexes of Mn, Co, Ni, Cu and Zn are oxygen-bonded while those of Cd, Hg and Pd are sulphur-bonded. The magnetic susceptibility and the optical spectral data reveal octahedral coordination for Mn, Co and Ni complexes. From the electronic spectra of Co and NI complexes, the ligand field parameters, Dq and β, are calculated.