Prabhakaran, C. P. ; Patel, C. C. (1968) Dimethyl sulphoxide and dimethyl formamide complexes of Mn(III) perchlorate Journal of Inorganic and Nuclear Chemistry, 30 (3). pp. 867-869. ISSN 0022-1902
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(68)80448-8
Abstract
Dimethyl sulphoxide (DMSO) and dimethyl formamide (DMF) complexes of Mn(III) perchlorate have been prepared and their conductivity, magnetic susceptibility and i.r. and electronic spectra studied. The complexes behave as uni-trivalent electrolytes in acetonitrile. Their magnetic moments of 5·1 B.M. show them to be of high spin type. Infra-red spectra show that oxygen is the donor atom in both complexes. The spin allowed electronic transition for d4 system, around 20,000 cm-1, ascribable to the 5Eg → 5T2g transition, suggests an octahedral configuration for these complexes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 33226 |
| Deposited On: | 30 Mar 2011 13:22 |
| Last Modified: | 10 Jun 2011 06:10 |
Repository Staff Only: item control page
