Terpenoids-LXII: the constitution of agarospirol, a sesquiterpenoid with a new skeleton

Varma, K. R. ; Maheshwari, M. L. ; Bhattacharyya, S. C. (1965) Terpenoids-LXII: the constitution of agarospirol, a sesquiterpenoid with a new skeleton Tetrahedron, 21 (1). pp. 115-138. ISSN 0040-4020

Full text not available from this repository.

Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82208-0

Abstract

Degradative studies and physical measurements supported by an unambiguous synthesis of the derived ketone (XVa) have led to the assignment of a novel spiro-skeleton to agarospirol (Ia), a sesquiterpene alcohol isolated from the essential oil of infected agarwood (Aquilaria agallocha Roxb.). The corresponding carbon skeleton (VI) has been named agarospirane. Agarospirol is the second spiro-terpenoid to be isolated from Nature. The most probable stereochemistry of agarospirol appears to be as in XXXIX.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:3256
Deposited On:11 Oct 2010 09:17
Last Modified:18 May 2011 08:44

Repository Staff Only: item control page