Varma, K. R. ; Maheshwari, M. L. ; Bhattacharyya, S. C. (1965) Terpenoids-LXII: the constitution of agarospirol, a sesquiterpenoid with a new skeleton Tetrahedron, 21 (1). pp. 115-138. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)82208-0
Abstract
Degradative studies and physical measurements supported by an unambiguous synthesis of the derived ketone (XVa) have led to the assignment of a novel spiro-skeleton to agarospirol (Ia), a sesquiterpene alcohol isolated from the essential oil of infected agarwood (Aquilaria agallocha Roxb.). The corresponding carbon skeleton (VI) has been named agarospirane. Agarospirol is the second spiro-terpenoid to be isolated from Nature. The most probable stereochemistry of agarospirol appears to be as in XXXIX.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 3256 |
Deposited On: | 11 Oct 2010 09:17 |
Last Modified: | 18 May 2011 08:44 |
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