Jayanthi, S. ; Kishore, K. (1996) Synthesis and characterization of poly(vinyl acetate peroxide) Journal of Applied Polymer Science, 59 (12). pp. 1887-1890. ISSN 0021-8995
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Official URL: http://www3.interscience.wiley.com/journal/60816/a...
Related URL: http://dx.doi.org/10.1002/(SICI)1097-4628(19960321)
Abstract
Poly(vinyl acetate peroxide) (PVACP) was prepared from vinyl acetate by free-radicalinitiated oxidative polymerization. The polyperoxide was isolated and characterized by different spectroscopic methods. The extreme instability of PVACP was demonstrated by FTIR spectroscopy. The 1H-and 13C-NMR studies show the irregularities in the polyperoxide chain due to the cleavage reactions of the propagating peroxide radical. Thermal degradation studies using differential scanning calorimetry revealed that PVACP degrades at a lower temperature and the heat of degradation is in the same range as reported for other vinyl polyperoxides.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 32103 |
| Deposited On: | 19 Mar 2011 11:44 |
| Last Modified: | 10 Jun 2011 06:18 |
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