Kishore, K. ; Nagarajan, R. (1981) Structure-thermal behaviour studies on the salicylato complex of cobalt Journal of Thermal Analysis and Calorimetry, 22 (1). pp. 25-32. ISSN 1388-6150
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Official URL: http://www.springerlink.com/content/m52612kxk82u37...
Related URL: http://dx.doi.org/10.1007/BF01915692
Abstract
The salicylato complex of cobalt was synthesized and its structure established to be [Co(sal)2]·4 H2O, where, sal =, from elemental analysis, IR spectroscopy, magnetic susceptibility, cryoscopy and conductivity. The X-ray diffractogram of the complex has been given. Thermal decomposition has been studied in air by thermogravimetry (TG), differential thermal analysis and differential scanning calorimetry. TG shows three main steps of decomposition. The intermediates formed at various stages were collected and analysed. From the TG results and chemical analysis of the intermediates, a mechanism has been proposed for the thermal decomposition of the complex, leading to the oxide formation in the final stage.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer. |
| ID Code: | 32009 |
| Deposited On: | 18 Mar 2011 14:32 |
| Last Modified: | 10 Jun 2011 07:08 |
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