Patil, K. C. ; Gajapathy, D. ; Kishore, K. (1982) Thermal reactivity of metal oxalate hydrazinates Thermochimica Acta, 52 (1-3). pp. 113-120. ISSN 0040-6031
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/004060...
Related URL: http://dx.doi.org/10.1016/0040-6031(82)85189-7
Abstract
Metl oxalate hydrazinates MC2O4·2 N2H4 where M=Mg, Mn, Fe, Co, Ni, Cu, Zn and Cd have been prepared and characterised by chemical analysis and infrared spectra. Thermal reactivity and decomposition of these oxalato complexes have been studied using thermogravimetry and differential thermal analysis. Hydrazinates of Mn, Fe, Co, Ni and Cu oxalates exhibit autocatalytic decomposition behaviour whereas the others do not. This phenomenon can be attributed to the presence of a bridged hydrazine as well as the thermal stability of the anhydrous metal oxalates.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 31890 |
Deposited On: | 18 Mar 2011 14:42 |
Last Modified: | 10 Jun 2011 07:11 |
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