Primary pyrolysis products of Thiokol liquid polysulfide

Ganesh, Kannan ; Kishore, Kaushal (1996) Primary pyrolysis products of Thiokol liquid polysulfide Macromolecules, 29 (1). pp. 26-29. ISSN 0024-9297

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ma9510451

Related URL: http://dx.doi.org/10.1021/ma9510451

Abstract

An analysis of the primary degradation products of the widely used commercial polysulfide polymer Thiokol LP-33 by direct pyrolysis-mass spectrometry (DP-MS) is reported. The mechanism of degradation is through a radical process involving the random cleavage of a formal C-O bond followed by backbiting to form the cyclic products.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:31702
Deposited On:19 Mar 2011 11:44
Last Modified:19 Mar 2011 11:44

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