Murugavel, Ramaswamy ; Singh, Mayank Pratap (2006) Novel layered copper phosphoramidate, which contains six-membered rings made of five different elements Inorganic Chemistry, 45 (23). pp. 9154-9156. ISSN 0020-1669
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic061298i
Related URL: http://dx.doi.org/10.1021/ic061298i
Abstract
Copper(II) perchlorate and (PhCONH)P(O)(OH)2 (H2bpa) react in methanol to yield [Cu(Hbpa)2]n, a novel layered solid that displays several interesting features. Unlike the previously reported copper phosphonates, a rare hexacoordination around the metal is observed in the title compound because of the amide C=O coordination to Cu in addition to the phosphoramidate P-O coordination. The six-membered chelate rings present in the title compound are made up of five different elements (Cu, P, C, N, and O).
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 30428 |
| Deposited On: | 23 Dec 2010 03:04 |
| Last Modified: | 23 Dec 2010 03:04 |
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