Cobalt and manganese nets via their wires: facile transformation in metal-diorganophosphates

Pothiraja, Ramasamy ; Sathiyendiran, Malaichamy ; Butcher, Ray J. ; Murugavel, Ramaswamy (2004) Cobalt and manganese nets via their wires: facile transformation in metal-diorganophosphates Inorganic Chemistry, 43 (24). pp. 7585-7587. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic048781i

Related URL: http://dx.doi.org/10.1021/ic048781i

Abstract

The manganese and cobalt complexes [M(dtbp)2]n (M = Mn, Co; dtbp = di-tert-butyl phosphate), which exist as one-dimensional molecular wires, transform to [M(dtbp)2(bpy)2·2H2O]n by the addition of 4,4-bipyridine (bpy) at room temperature; the latter compounds form noninterpenetrating rectangular grid structures.

Item Type:Article
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Deposited On:23 Dec 2010 03:04
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